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ADVANCE - GRANULAR ANT BAIT, FORMULA 1
001 07/02/97 ADVANCE - GRANULAR ANT BAIT, FORMULA 1
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PRODUCT IDENTIFICATION/INFORMATION
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PRODUCT NAME: ADVANCE - GRANULAR ANT BAIT, FORMULA 1
MSDS NUMBER: P19407VS
DATE ISSUED: 2/23/97
SUPERSEDES: NEW
ISSUED BY: 009118
EMERGENCY PHONE NUMBER: (800-424-9300
EPA REG NO: 499-467
SECTION 1. HAZARDOUS INGREDIENTS
Active Ingredients: ACGIH ACGIH OSHA
Abamectin: 0.05% (CAS #71751-41-2) TLV/TWA STEL PEL TLV/PEL
(A mixture of avermectins containing N E N E N E 40 mcg/ml*
>= 80% avermectin B1A (5-0-demethyl
avermectin A1A) and <20% avermectin
B1B (5-0-demethyl-25-de(l-methyl-
propyl)-25-(l-methylethyl) avermectin
A1A). s
INERT INGREDIENTS
Soybean oil** (CAS # 8001-22-7) N E N E N E N E
Corn grits: ** N E N E N E N E
t-butyl hydroquinone**: (CAS # 1948-33-0) ) N E N E N E N E
* exposure limit recommended by manufacturer of active ingredient.
** Not defined as a hazardous ingredient according to OSHA hazard
communication Regulation: 1910.1200
All components of this product are listed or excluded from listing on the US
Toxic Substances Control Act (TSCA) Chemical Substance Inventory.
SECTION 2. PHYSICAL DATA
Boiling Point: NA
Specific Gravity (H20 = 1): NA
Vapor Pressure: NA
Percent Volatile: ND
Bulk Density: ND
Vapor Density: NA
Evaporation Rate: NA
Solubility in Water: Insoluble
Appearance and Odor: A granular corn grit bait with yellow color.
SECTION 3. FIRE AND EXPLOSION HAZARD DATA
Flashpoint: NA
NFPA 30B Flammability: NA
LEL: NA UEL: NA
Flammable Limits: NE
Extinguishing Media: C02, Dry Chemical, foam
Special Firefighting Procedures: Respiratory protection is recommended for
fire fighters.
Excessive use of water may create excess run-off water which may lead to
contamination of the environment. Follow environmental and personal safety
precautions noted for spill or leak.
Unusual Fire and Explosion Hazards: Material will burn if ignited.
SECTION 4. HEALTH HAZARD DATA
Health Hazard (Acute and Chronic) - Signs and Symptoms of exposure:
Eye: May cause some reversible eye irritation. Caused slight conjunctival
irritation in albino rabbits reversible in seven days. Caused a dull cornea
in albino rabbits reversible in three days. No iritis was observed.
Skin: Non-irritating to skin. Primary irritation = 0.0 for albino rabbits.
Acute Dermal toxicity - LD5o > 2.0 g/kg in albino rabbits.
Ingestion and inhalation: Acute oral toxicity - LD50 > g/kg in albino rats.
Bait particles are not respirable.
Carcinogenicity:
NTP? IARC Monograph? OSHA Regulated?
N o N o N o
Emergency and First Aid Procedures:
If on Skin: Remove contaminated clothing and wash affected areas with
soap and water.
If in Eyes: Flush eyes with plenty of water. Call a physician if irritation
persists.
If swallowed: Call a physician or poison control center. Give 1 or 2
glasses of water and immediately induce vomiting by gently touching back of
throat with finger or administer syrup of Ipecac. Do not give anything
by mouth to an unconscious person. Get medical attention.
SECTION 5. REACTIVITY DATA
Stability: Stable under normal conditions.
Conditions to Avoid: None known.
Incompatability (materials to Avoid): Abamectin can be hydrolyzed by strong,
caustic solution.
Hazardous Decomposition Products: If involved in a fire,
toxic gases including CO, C02, toxic dust and smoke may be generated.
Hazardous Polymerization: None known.
SECTION 6. SPILL OR LEAK PROCEDURES
Steps to be taken in case material is released or spilled-
Spilled material should be carefully collected and containerized in a manner
that produces the least amount of airborne dust. Suitable protective
equipment should be worn during any spill clean-up operation. Residual
surface material may be removed with towels moistened with methanol.
Emergency Telephone Number of CHEMTREC: (800) 424-9300
(for transportation spills)
Environmental Hazards/Waste Disposal Method:
This pesticide is toxic to fish and wildlife. Do not apply directly to water,
to areas where surface water is present, or to intertidal areas below the mean
high water mark. Do not contaminate water when disposing of equipment
washwaters.
Container disposal:
Follow label instructions for container disposal.
In case of spillage this product is subject to reporting requirements of the
Comprehensive Environmental Response, Compensation, and Liability Act
(CERCLA).
SECTION 7. SPECIAL PROTECTION INFORMATION
Respiratory Protection: NA.
Ventilation:
Local Exhaust:NA. Mechanical: NA
Special:NA. Other: NA
Protective Gloves: Protective gloves may be worn when handling the
formulation.
Eye Protection: None required.
Other Protective Equipment: None required.
SECTION 8. SPECIAL PRECAUTIONS
Precautions to be taken in handling and storage: HAZARDS TO HUMANS AND
DOMESTIC ANIMALS
CAUTION. Harmful if swallowed or absorbed through skin.
Avoid contact with eyes, skin or clothing. Always wash hands thoroughly with
soap and water after handling. Wash all contaminated
clothing thoroughly. Do not contaminate kitchen utensils with this product.
Pets may be attracted to this product. Keep out of reach of children. for
bulk materials, protective coveralls and boots should be worn to protect
against accidental contamination. personal protective items should be cleaned
after each application. Store in a cool, dry place which is inaccessible to
children, pets, livestock or wildlife. Do no store near heat or flame.
Store in a tightly closed container. Do not reuse empty container.
Other Precautions:
When handling on a regular basis, shower and a clean change of clothes are
recommended at the end of the work day. Wash hands before eating, drinking or
smoking. For use on non-cropland only. Do not treat grazing fields. Apply
when ants are actively foraging. This is usually when soil temperatures are
above 60 F. Avoid application during excessive hot periods of the day or when
the grass is wet from rain or heavy dew. Crops treated with Advance must not
be used for food or feed until residue tolerance for this chemical has been
established or until the appropriate laws and regulations of the country of
use have been established.
SECTION 9. HEALTH RATING INFORMATION (NFPA)
Health - 1 Flammability - 1 Reactivity - 0
SECTION 10. SARA TITLE III / SECTION 313 SUPPLIER NOTIFICATION
This product contains the following toxic chemical subject to the reporting
requirements of section 313 of the emergency planning and community right-to-
know act of 1986 and of 40 CFR 372:
CAS# Chemical Name % by weight
71751-41-2 Abamectin 0.011
SECTION 11. DOT SHIPPING INFORMATION
Proper Shipping Name: na
Hazard Class: na
NA - Not Applicable
ND - Not Determined
NE - Not Established
PEL - Permissible Exposure Limit
ACL - Acceptable Ceiling Level
MPC - Maximum Peak Concentration
For emergency assistance involving chemicals,
call CHEMTREC - (800) 424-9300
Univar USA
6100 Carillon Point, Kirkland WA 98033 - (425) 889-3400
Univar USA expressly disclaims all express or implied warranties of merchantability and fitness for a particular purpose, with respect to the product or information provided herein, and shall under no circumstances be liable for incidental or consequential damages.
All information appearing herien is based upon data obtained from the manufacturer and/or recognized technical sources. While the information is believed to be accurate, Univar USA makes no representations as to its accuracy or suffiency. Conditions of use are beyond Univar USA's control and therefore users are responsible to verify this data under their own operating conditions to determine whether the product is suitable for their particular purposes and they assume all risks of their use, handling, and disposal of the product, or from the publication or use of, or reliance upon, information contained herein. This information relates only to the product designated herein, and does not relate to its use in combination with any other material or in any other process.
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